2005-01-3413
A New Approach for Single Stage Ascent to Orbit
Silane Fuel in a New Vehicle Design
David Padanyi-Gulyas and Andras D. Bodo
Nitronics Aerospace Technologies, LLC
Copyright © 2005 SAE International
ABSTRACT
MAIN SECTION
Spacecraft designs incorporating a propulsion system
powered by a more efficient fuel would greatly reduce
the oxidizer to payload ratio. This could be accomplished
with a single-stage vehicle that uses air while in the
atmosphere and switches to onboard oxidizer only after
reaching the upper limit of the atmosphere. In this
presentation, a revolutionary new vehicle is proposed
that incorporates silane-based fuels into an air-breathing
spacecraft design that achieves orbit via low ascent
angles, where it then switches to onboard oxidizer. A
ceramic and alloy propulsion system takes advantage of
the properties of silane, utilizing both the oxygen and the
80% nitrogen of the atmosphere for combustion.
LOW-ANGLE LAUNCHING APPROACHES,
BACKGROUND
INTRODUCTION
Using a revolutionary new engine design is the basis of
the vehicle proposed in this presentation: in contrast to
jet engines, this innovative new turbine-less engine
design uses intelligent pressure management for
nitrogen combustion to produce the energy for achieving
speeds past 9,000 mph. To use this new propulsion
system and achieve these speeds in the atmosphere,
the aerodynamic design of the vehicle mimics the wing
of a supersonic jet in all of its cross-sections. This
rotation-symmetric, disk-like design addresses the air
with a knife-edge silhouette that minimizes friction and
heat produced by these speeds. Increasing speed of the
vehicle makes up for decreasing density of the air until it
reaches escape velocity at the edge of the atmosphere.
While reentering the atmosphere, the compact and
robust shape of the discus and the outer rotating
protection ring, made of silicone nitride and silicone
carbide, distributes the kinetic energy and the heat to
allow slowing to speeds seen in normal jet aircraft. By
then, after opening the protecting covers, a wreath of
counter-rotating internal blades are used to touch down
vertically; the same way, lift-up is accomplished. In
another presentation at this conference we will learn of
the exciting capabilities and advantages of silane fuels
that can be used in this innovative spacecraft design.
Our traditional, vertically launching, three-stage space
carrier systems, all based on the well known rocket
equations, represent a highly inefficient fuel to payload
ratio, partly because of the necessity of carrying fuel
AND oxidizer all their way along. Refueled, the three
stages make up about 97 per cent of the entire take-off
weight. In the case of the moon rocket Saturn V, this
amounted to nearly 3,000 tons! Each time the fuel
content of one stage is consumed, it is disposed of and
the next stage takes over for further acceleration. The
disposed ballast, as part of the most modern technology
of mankind, burns up in the terrestrial atmosphere.
Nevertheless, this was the method for the greatest
triumph in the history of manned space travel. In view of
this success, the exorbitant cost involved, especially in
cold war competition, was rather minor. But even then,
serious research efforts were made to replace this
expensive habit of disposal by reusable systems.
Quite early, then, in the sixties of the last century,
Eugene Saenger and his assistants proposed a
completely reusable spacecraft: using the aerodynamic
air lift like an airplane, his two-stage system would lift off
horizontally, thus overcoming the rocket equation. This
way, the engines did not have to carry the entire weight
of the missile but ensure only horizontal acceleration
(Fig. 1).
Fig. 1
The intention was to accelerate the delta-shaped carrier
up to a speed of approximately 3,700 mph. Then, at the
altitude of about 20 miles, the strapped-on rocket plane
would be separated and produce the necessary speed
to reach orbit on its own (Fig. 2).
Fig. 4
Fig. 2
A propulsion system with an innovative jet drive that
would use air instead of oxidizer for combustion so that
an enormous weight reduction would be possible was
proposed also: ramjet propulsion. Different from ordinary
airplane turbines, this drive has no rotating parts and
theoretically allows a multiple of the speed of sound.
Liquid hydrogen and the roughly 20% oxygen portion of
the air would create the combustion. The forward
propulsion of the flying object itself would provide the air
compression necessary for efficient oxidation (Fig. 3).
Fig. 3
However, the ramjet develops pressures high enough for
combustion only at speeds over Mach 3. For lower
speeds of launching and landing, a turbine had to be
integrated. Complex mechanisms to reroute the air
stream should enable the switching between the two
drives (Fig. 4).
The development of a reliable technology for this highly
complex apparatus was finally estimated as too timeconsuming and risky by NASA - the space shuttle was
built instead. The carrier plane was simply replaced by
the reliable rocket technology. Since the space shuttle
system - still launching vertically - relies on the rocket
equation again, both fuel and oxidizer have to be carried
along and the empty fuel tank has to be discarded, just
as before.
The two booster rockets are separated within the
atmosphere and fall back into the sea slowed down by
parachutes. Their propagated reusability is questionable,
however, after the tragic incident, when refurbished
boosters caused an explosion. Nowadays the only part
reused is the orbiter itself, which soars back to earth after
the mission. Much effort is needed, however, before the
space shuttle can be launched again, for transport back to
the lift-off area and for extremely thorough inspection. The
numerous ceramic tiles, which are glued or screwed on,
need extra special attention since they have to protect the
vehicle against the inferno of re-entry. This way it takes
months for general overhaul before the space shuttle is
ready for take-off once more.
The total costs for launching this two and a half
thousand ton construction exceeds even the costs of
conventional rockets, which burn up totally. But the price
we pay for these achievements is not only monetary: the
ozone layer of our planet is considerably injured each
time the booster rockets of the space shuttle burn their
fuel. That sounds relatively harmless in comparison to
the high risk of the carcinogenic fuels used in the
European Ariane carrier rockets.
It has become an urgent matter to come up with
appropriate solutions. Again, Saenger’s concept with its
horizontal launch is being discussed as one of the most
favored. This type of space flight seems to be an elegant
alternative; however, the system‘s most critical aspect is
the air-breathing ramjet, which appears to turn out
unsuccessful because of one important aspect:
Hydrogen is the ideal fuel for the air-breathing ramjet. It
reacts with the 20% oxygen of the air to build water steam.
The major part of the atmospheric gas is nitrogen (80%)
with its characteristic of a mutual triple bond, which is why
it doesn’t participate in chemical reactions. This is
significant, because normally a triple bond in a chemical
compound is highly reactive. Because nitrogen is heated
along with all other parts of the atmospheric gases without
reacting, it is the cause for the diminishing efficiency of the
engines. Furthermore hydrogen uses up a multiple of
volume compared to other fuels, which drastically affects
size and thus weight of the entire missile carrying the fuel.
And to top it off, hydrogen’s boiling point is as low as
-252° C and can only be kept at this extremely low
temperature with an enormous effort. The geometry of
suitable fuel containers is difficult to match with the
shape of the carrier aircraft.
However, there is also the orbiter, which is disconnected
at an altitude of 20 miles. For its atmospheric traveling
part, it should be long and pointed. This geometry is the
opposite of what it should be during the re-entry phase,
when a compact plump shape is favorable because it
needs to withstand enormous thermal and mechanical
strain. The compromise of the two geometries would
look not much different than the space shuttle. Such a
plump and heavy construction causes immense
resistance and is the cause for inefficient supersonic
performance.
The greatest disadvantage results from the shape or
rather the way aircrafts are constructed: the rib frame
technique from ship building, forming a light and flexible
shell (Fig. 5).
chamber, will burn with the 80% nitrogen part of the
atmosphere. This was discovered and patented in 1994 at
the University of Cologn by Dr. Peter Plichta.
Air-breathing rocket drives using not only oxygen for
combustion but also its 80% nitrogen component will
initiate a new era of propulsion systems (Fig 6).
Fig. 6
The nitrogen utilization turns combustion kinetics upside
down because it has the characteristics of an implosion.
This revolutionary combustion method needs a newly
conceived ceramic engine, which could be trend-setting
for future jet engines. In contrast to common jet drives,
this innovative design together with a new construction
method eliminates rotating elements such as turbine
wheels, regardless of the craft’s speed. Clever
management of the pressure automatically supplies the
drive with the amount of air necessary for oxidation,
which is uniquely possible because of the nitrogen
combustion (Figs. 7 and 8).
Fig. 5
This flexible wing construction is a great disadvantage
during the stresses of re-entry. The utmost consequence
would be complete failure, when minor twisting forces
would destroy the protective ceramic layer and would
expose the vehicle to extreme conditions. That is why
the ceramic protection shield must consist of many small
tiles to better compensate for vibrations and shearing
forces. Such a construction in re-entry is strained to the
limit and a failure like that of Columbia could happen.
Fig. 7
AIR-BREATHING PROPULSION ENGINE, USING
SILANE
All those problems of space flight make us aware of the
fact that of the current technology has reached its
limitations. Refinement and further development would
increase expenses while there is no guarantee for more
reliability or profitability. The only way out of this technical
dead end is to reform space flight totally. One condition
was the discovery of a new fuel called silane. The chemical
and thermodynamic characteristics of silanes will be
introduced in another presentation at this conference. Only
the most important characteristic of the silanes has to be
emphasized here: their silicon atoms, in a hot combustion
Fig. 8
This highly efficient air-breathing drive enables the
space craft to accelerate past 9,000 mph within the
atmosphere. Before, such speed was possible only with
conventional missile drives, which had to lift and
accelerate the extra weight of the oxidizer as well. For
reasons of patent protection, more details cannot be
disclosed.
blades at the perimeter stabilize the vehicle horizontally
using the principles of precession (Figs. 11 and 12).
A NEW DESIGN FOR A COMPACT, SINGLE-STAGE
SPACECRAFT
To move through atmospheric gas at such a high speed,
the shape of the aircraft needs to have excellent
aerodynamic performance. The outline chosen is similar
to that of a wing profile of a supersonic jet, which literally
cuts through the air. This profile is rotated around a
vertical axis, providing each cross-section of the body
with a supersonic geometry.
Fig. 11
The result is a new propulsion concept combined with an
extremely compact missile, which cannot be compared
any more with any conventional flight apparatuses of
any type (Figs. 9 and 10).
Fig. 12
Fig. 9
To reach orbit, simple horizontal acceleration is required.
At a speed of approximately 200 mph, the cover of the
rotors is closed and the vehicle is propelled horizontally
by the air-breathing engines. Beneath the covers, the
rotors continue to move with flat blades to further
stabilize horizontally, while the air craft continuously
accelerates and rises. The rotating outer rings of the
discus also distribute thermal stress, generated at the
air-vehicle interface to minimize the heat at the leading
edge as speed increases (Figs. 13 and 14).
Fig. 10
Like a helicopter, it can lift off vertically: the uplift is
created by counter-rotating adjustable internal rotor
blades at the perimeter of the vehicle. This provides for
incredible maneuverability that, combined with the
completely symmetrical discus design, is aerodynamic in
any direction. In addition, the counter-rotating rotor
Fig. 13
To guarantee continuous efficiency of the jet drive, the
force of the increasing speed compensates for
decreasing air pressure.
After slowing to below sonic speed, with re-opened
covers, the rotating internal blades are used to touch
down vertically. After a short safety check, the discus
can be refuelled and reloaded for the next mission. The
costly general overhaul, such as needed by the shuttle,
is usually not necessary.
Fig. 14
Therefore, up to an altitude of 30 miles, sufficient air will
be pressed into the drive and the air-breathing engines
will accelerate up to Mach 15. As the discus approaches
the escape velocity of earth's gravity, in the thin
atmosphere at that altitude, the engines can be powered
by a small amount of onboard oxidizer to achieve the
added speed necessary for orbit.
To return to earth, the shape of the discus and the outer
rotating ring made of silicone nitride and silicone carbide
distributes the kinetic energy and the heat of reentry to
allow slowing to speeds seen in normal jet aircraft. The
shape of the discus correlates optimally to the
requirements of re-entry. It is compact and extremely
resistant to shearing forces. This is supported by the
innovative construction without framework or tiles.
The high tech construction materials used are porous,
very strong, with perfect thermal and sonic isolation
properties, and are very lightweight: they float in water.
The clever composition of metal and ceramic foams
allows a layer-like outer shell that is assembled like a
sandwich, and it protects the interior effectively against
heat, radiation, and mechanical impacts (Fig. 15).
Fig. 16
CONCLUSION
FURTHER USES
Experts predict a high demand for high speed airplanes,
especially for passenger flights now that the only
supersonic commercial plane of the world, the
Concorde, has been discarded because of its age. This
revolutionary and innovative concept will also be used to
design vehicles that fly at incredible altitudes. Via the airbreathing jet drive accelerated to eight times sonic
speed, it would then glide on the air like a flat stone on
water and carry passengers from New York to Beijing in
only 2-3 hours.
PERSPECTIVES
In the process of the discus development, a technically
detailed computer model is being developed, electronic
data from which is to be used for the first remote control
functional prototype with a diameter of 150cm. This
model is supposed to convey the unique
maneuverability. Simultaneously, different production
and material technologies are to be tested and optimized
that finally will lead to a full-size affordable aircraft.
Fig. 15
The rotating outer ring distributes the friction heat during
the process of re-entry (Fig. 16).
Step by step upward scaling is to result in a functional
prototype. Within a few scaling steps and a few years, a
prototype with a diameter of 20m for space flight could
be completed, which could even carry freight into orbit.
The final size, to bring up to 100 passengers into space
and back, would be of far greater diameter.
ACKNOWLEDGMENTS
The authors want to thank hereby in general all persons
and institutions involved in the preparation of this
presentation for their valuable and highly appreciated
support: David Zornes invitation to SAE WAC, Peter
Plichta, Erika Kirgis, Franz Willi, and Linda Bell Carlson.
CONTACT
Nitronics Aerospace Technologies, LLC
3116 S.W. 153rd Drive
Beaverton, Oregon 97006
REFERENCES
̇
̇
̇
Benzin Aus Sand / Die Silan-Revolution
(Fuel, made of Sand / The Silane-Revolution)
by Peter Plichta, Langen-Müller Press, 2001
NET-Journal (Switzerland) Vol. 7/2002, pg 4ff
Raum&Zeit (Germany) Vol. 115/2002, pg.74ff
2005-01-3412
Silicon Based Fuels for Space Flight
David Padanyi-Gulyas and Andras D. Bodo
Nitronics Aerospace Technologies, LLC
Copyright © 2005 SAE International
ABSTRACT
Limiting factors in air and space propulsion systems
affect both design and operation of the engines and the
energy derived from a fuel source. Translation of the fuel
source to energy (combustion) always requires an
oxidizer. The process of breaking the energy-laden
bonds of the fuel has classically been achieved using
the oxygen in air for air-breathing engines or an onboard
source of oxidizer for spaceflight. This is a critical
limitation for a possible single-stage vehicle, because
the weight of the fuel and oxidizer needed to achieve the
necessary speed and altitude for orbit is excessive. This
problem was overcome using multi-stage engines that
are discarded sequentially during vertical ascent.
However, the relative inefficiency of fuels currently
available perpetuates the requirement for multi-stage
engines to achieve orbit. Multi-stage rockets still require
onboard fuel and oxidizer at lift-off that can account for
over 95% of the lift-off weight. Only with more efficient
fuels and propulsion systems will it become possible to
achieve orbit and spaceflight without this limitation. More
effective spacecraft designs incorporating a propulsion
system powered by a more efficient fuel would greatly
reduce the oxidizer to payload ratio. This could be
accomplished with a vehicle that uses air while in the
atmosphere and switches to onboard oxidizer only after
reaching the upper limit of the atmosphere. This more
efficient fuel is now available. The use of silanes
(silicone hydrites) provides the fuel necessary to achieve
this radically different and efficient means of propulsion,
using both the oxygen and the 80% nitrogen of our
atmosphere for combustion.
INTRODUCTION
Silanes or silicon hydrates are similar to fossil fuels. The
element silicon is located directly below carbon in the
system of chemical elements, which indicates a
chemical behavior similar to carbon. It can also connect
to longer chains.
Fossil fuels are composed of a shorter or longer chain of
carbon atoms along with a pair of hydrogen atoms
connected (Fig. 1).
Fig. 1
The simplest of the hydrocarbons is methane. It consists
of one carbon atom connected to four hydrogen atoms:
CH4.
Silanes, likewise, are composed of a chain of silicon
atoms, again with a pair of hydrogen atoms connected
(Fig. 2).
Fig. 2
The simplest representative of the silanes is monosilane,
with four hydrogen atoms: SiH4, with a boiling point of 112°C. The first four silicon hydrates, already discovered
at the beginning of the last century, self-ignite in air. Triand tetrasilane are gasoline-like liquids.
Longer chains of silanes, however, were supposed to be
unstable and thus not producible. In fact, this opinion
about longer chained silanes is still present in most
chemical institutes and publications; the discoverer of
the so-called lower silanes, Prof. Alfred Stock, has
stated this in his "Hydrides of Boron and Silicon" (Cornell
University Press, 1933). Stock could never succeed with
the isolation of pentasilane (Si5H10, Fig. 3).
Fig. 3
MAIN SECTION
The higher silanes, i.e. silanes with five and more silicon
atoms in their chains, were successfully synthesized for
the first time in 1970 at the University of Cologne, by
Dr. Peter Plichta.
The so-called higher silanes turned out to be stable.
From seven Si atoms upward they no longer self-ignite.
Together with their oily property they became easier to
handle. Increasing chain length means more thermal
stability and more power. This is the prerequisite for a
potent fuel with a high power density.
SILANE COMBUSTION
Silanes – of all lengths – burn with the air’s oxygen to
form brown silicon monoxide. Shown below is the
combustion of pentasilane, filmed during laboratory tests
at the University of Dortmund, broadcasted also on TV
for the first time in January 2002 (Figs. 4 and 5).
Fig. 6
High temperatures in a combustion chamber initiate the
Si atoms to aggressively attack the remaining nitrogen
(Fig. 7). This was discovered only in 1994 by Dr. Plichta.
Fig. 7
Nitrogen Combustion
Fig. 4
Nitrogen has the chemical formula N2 and consists of
two nitrogen atoms connected by a triple bond. Triple
bond connections are known to chemistry and chemical
engineering as quite unstable, and so are easy to break
up. Not so the triple bond connection of the nitrogen
molecule, which is extremely stable. This unique and
unexplainable behavior of the triple bond of the nitrogen
molecule makes this gas an ideal and commonly used
protecting medium for many chemical processes (even
its name reflects this in some languages: "suffocating" or
"extinguishing substance"). In a silane combustion
chamber, however, the unbound and unconnected hot
silicon atoms break the nitrogen molecule bond easily
(Fig. 8).
Fig. 5
But silanes have another property that remained hidden
for decades.
Silanes, like regular fossil fuels, are carriers of hydrogen.
In regular engines, the hydrogen part of the silanes
reacts with oxygen (Fig. 6).
Fig. 8
Together they form - exothermally - the combustion
product: silicon nitride (Si3N4). This substance carries
four pairs of electrons positioned in tetrahedron
geometry (Fig. 9) and by definition can be considered a
solid inert “rare gas”.
carbon part of the hydrocarbon burns, again only with
oxygen: a gas, carbon dioxide, is produced. The
nitrogen part of the atmosphere (80%; the thickness of
the downward pointing arrow demonstrates the relation
of the volumes) does not participate in the combustion at
all. On the contrary, its presence is a disturbing and
cooling factor in the reaction and absorbs a very
valuable part of the produced energy of the combustion.
Next, the combustion of silicone hydrates is demonstrated (Fig. 11):
Fig. 9
Commonly, oxidation means the reaction with oxygen,
from which the name stems. Oxidation with nitrogen
caused fierce controversy among specialists, when a
dangerous near disaster proved this new discovery: one
of the greatest silicon producers of the world confirmed
the reaction of activated silicon and nitrogen under
pressure. Even the press reported this incident.
Traditional fuel oxidation, the combustion
hydrocarbons, is shown below (Fig. 10):
of
Fig. 11
Beginning the combustion, the 20% oxygen part of the
air burns the hydrogen part of the silane to water (H2O).
This is analogous to hydrocarbon combustion. The hot
silicon radicals of the silane then become highly
activated and burn with the nitrogen part of the
atmosphere, producing silicon nitride (Si3N4). The
inflowing air can be used in a stoechiometrically
complete manner, when the silane fuel becomes
enriched, e.g. with silicon dispersion. This revolutionary
nitrogen reaction was proven at the facilities of one of
the greatest silicon producers of the world (Fig. 12).
Fig. 10
In a first step, the 20% oxygen part of the air burns the
hydrogen part of the fuel, producing water (H2O). The
Fig. 12
SPECIFICATIONS AND PROPERTIES OF SILANES
Higher (longer chained) silanes, beginning with
heptasilane (Si7H16), are stable oily liquids. They can be
pumped and are not self-igniting with air. Some most
important specifications of silanes compared to
hydrocarbons can be seen in Table 1 vs. Table 2.
Hydrocarbons
material
(hydrocarbon)
methane
CH4
ethane
C2H6
propane
C3H8
butane
n-C4H10
i-C4H10
pentane
n-C5H12
Cyclo-C5H10
hexane
n-C6H14
Cyclo-C6H12
heptane
n-C7H16
octane
n-C8H18
The densities of the silicon hydrates (important for a
better weight / volume ratio) are considerably higher as
well. The reaction enthalpies are, contrary to the
hydrocarbons, positive.
boiling
point
[°C]
∆ Hf
[kJ/mol]
density
[g/cm3]
-182.5
-161.5
-74.898
0.424
MEASUREMENT OF SILANE COMBUSTION
-183
-88
-84.727
-187.7
-42
0.5003
After producing higher silanes in quantities for
calorimetric measurements, an initial investigation could
be accomplished at the «ICT» (the Frauenhofer Institute
in Berghausen near Karlsruhe).
-135
-159
-0.5
-11.7
0.579
-130
-94
+36
+49
0.6262
0.746
-95
-80
+68.7
+83
0.66
0.81
-90.7
+98.4
0.681
-57
+126
0.703
Table 1
monosilane
SiH4
disilane
Si2H6
trisilane
Si 3H8
tetrasilane
n-Si 4H10
i-Si 4H10
pentasilane
n-Si 5H12
Cyclo-Si 5H10
hexasilane
n-Si 6H14
Cyclo-Si 6H12
heptasilane
n-Si 7H16
octasilane
n-Si 8H18
Freezing and boiling points of silanes are significantly
higher than those of the corresponding hydrocarbons.
freezing
point
[°C]
Silanes
material
(silane)
reactions, e.g. building molecules of longer chains.
Positive values signalize endothermic reactions (needing
thermal energy), while negative signs show exothermic
behavior (giving thermal energy).
freezing
point
[°C]
boiling
point
[°C]
∆ Hf
[kJ/mol]
-184.7
-112.3
+34
-129.4
-14.8
+80
-117.4
+52.9
+121
0.739
-89.9
-99.4
+108.1
+101.7
+175
+180
0.795
-72.2
-10.5
+153.2
+194.3
+226
0.827
0.746
-44.7
+16.5
+193.6
+226
+268
0.847
-30.1
+226.8
density
[g/cm3]
0.859
n.a.
Table 2
The reaction enthalpy ( ∆Hf) reflects the thermal energy,
which will be unbound while running through chemical
The most important characteristics of some known fuels
and oxidizers, along with a representative of the silanes,
are shown in the next comparative table (Table 3).
During these measurements, cyclopentasilane (CPS)
was reacting (burned) merely with oxygen. Its specific
impulse was already very high, even in this isolated
stage of oxidization. The value is nearly identical to that
of kerosene and the comparison with hydrazine (ADMH)
shows minor differences as well. The second step of
oxidization, the reaction of hot silicon with nitrogen,
made the specific impulse of the silanes even more
advantageous.
composition
(fuel &
oxidizer)
fuel
[%
wgt]
CPS & O2
oxidizer
[% wgt]
specific
impulse
[N
sec/kg]
adiabatic
combustion
temp[°K]
25.41
6
74.584
2886
2863
H 2 & O2
11.19
0
88.810
3632
3684
RP1& O2
22.69
3
77.307
2890
3736
ADMH &
N2O4
24.61
9
75.381
2777
3420
ADMH & O2
31.92
5
68.048
2997
3662
Table 3
Abbreviations for fuels and oxidizers:
CPS = cyclopentasilane (Si5H10)
RP1 = kerosene
ADMH = asymmetric 1.1 dimethylhydrazine
O2 = oxygen
N2O4 = dinitrogentetraoxide
Besides this, there are more very positive features of
silanes. The specific density of silanes is higher then the
density of the corresponding hydrocarbons. Silanes are
completely non-toxic, while hydrazine for example is
highly carcinogenic. The combustion products of silanes,
water and silicon nitride, are non-toxic too and will not
represent any atmospheric pollution menace. Silicon
nitride can be further used easily with simple chemical
transformations.
USE OF SILANES IN AIR BREATHING PROPULSION
SYSTEMS
This newly discovered "oxidation" of silane fuel with
nitrogen, the major part of the atmosphere, opens
completely new perspectives for air-breathing rocket
drives, which not only use oxygen for combustion but
also the rest of air, i.e. the 80% nitrogen as well. This
chemical reaction with nitrogen provides a new fuel with
incredibly high energy, making it possible to design more
powerful propulsion systems for high altitude flight and
for totally new concepts in spacecraft design.
For combustion engines, jet engines, hypersonic ramjets
and even scramjets, the nitrogen combustion turns
known combustion dynamics upside down, because it
has the characteristics of an implosion. This
revolutionary combustion method needs a newly
conceived ceramic engine, which could be trend-setting
for future engines. For reasons of patent protection,
details cannot be disclosed.
In contrast to common jet drives, this innovative design,
together with a new construction method, allows
propulsion without rotating elements such as turbine
wheels, regardless of the craft’s speed. Clever
management of the pressure automatically supplies the
drive with the exactly calculated quantity of air
necessary for oxidation, which is uniquely possible
because of the nitrogen combustion.
PRODUCTION OF SILANES
As the synthesis of higher silanes was accomplished, it
was demonstrated that with increased chain length, they
become more stable, have an oily property, are not selfigniting, so not dangerous - in contrast to the current
opinion of chemists. The basic production methods for
measurement volumes are well established and proven.
For industrial volume production, all production steps,
along with feasible variants, are outlined and patented.
CONCLUSION
PERSPECTIVES: THE "INORGANIC CYCLE"
The basis for the production of silane is silicon. Silicon
is, following oxygen, the second most abundant element
found in Earth's crust. Two thirds of our environment is
based on structures of some derivates of silicates, i.e.
silicon connected to oxygen, forming sand and rock.
Establishing huge silane production facilities, preferably
in sun-belt deserts, where electric energy for the
production can be gained directly from widely set solarcell plants, plus optimized industrial procedures (like the
patented Modified Mueller-Rochow-Synthesis) can
deliver a very powerful fuel of inexhaustible resources:
silicon, commonly sand. By using (burning) this fuel in
air breathing rocket jet engines or – for terrestrial
movements – in (also well patented) Silane-DieselWankel engines, all combustion products (water and
silicon nitride) are stable, non-toxic and completely
recyclable. All recycling steps of various possibilities,
according to local or global needs, result in energy (e.g.
burning methane, synthesised from silicon nitride) or in
natural final materials (like water or nitrogen) not
representing any stress to the environment at all. Thus,
an artificial inorganic silicon cycle will occur, just as
nature operates the well-known organic carbon cycle,
keeping balance in Earth's resources (Fig. 13, on the
following page).
Silane fuels provide the basis for spacecraft designs that
incorporate a gradual ascent to space by using both the
oxygen and the nitrogen in the air until reaching the limit
of the atmosphere. At the limit of our atmosphere, only
minimal volumes of onboard fuel and oxidizer would be
required to continue to orbit.
ACKNOWLEDGMENTS
New and innovative propulsion systems using these
more efficient fuels are the basis for completely new
spacecraft designs that do not require the compromises
of aerodynamic principles currently necessary to
accommodate the ascent to and descent from orbit. New
spacecraft designs that incorporate these more efficient
propulsion systems will lead to vehicles that can achieve
orbit via low ascent angles and without multi-stage
engines. Such an innovative spacecraft design will be
proposed in another presentation at this meeting by the
same authors.
REFERENCES
The authors want to thank hereby in general all persons
and institutions involved in the preparation of this
presentation for their valuable and highly appreciated
support: David Zornes’ invitation to SAE WAC, Peter
Plichta, Erika Kirgis, Franz Willi, and Linda Bell Carlson.
̇
̇
̇
Benzin Aus Sand / Die Silan-Revolution
(Fuel, made of Sand / The Silane-Revolution)
by Peter Plichta, Langen-Müller Press, 2001
NET-Journal (Switzerland) Vol. 7/2002, pg 4ff
Raum&Zeit (Germany) Vol. 115/2002, pg.74ff
CONTACT
Nitronics Aerospace Technologies, LLC
3116 S.W. 153rd Drive Beaverton, Oregon 97006
APPENDIX
Fig. 13